80. Q. Qiu, Q. Qi, J. Usuba, K. Lee, I. Aprahamian,* G. G. D. Han,* Visible Light Activated Energy Storage in Solid-State Azo-BF2 Switches, Chem. Sci. 2023, in press Part of the 2023 Chemical Science HOT Article Collection |
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77. A. N. Bismillah, I. Aprahamian,* Boron difluoride hydrazone (BODIHY) complexes: A new class of fluorescent molecular rotors, J. Phys. Org. Chem. 2023, e4485 |
76. G. C. Thaggard, G. A. Leith, D. Sosnin, C. R. Martin, K. C. Park, M. K. McBride, J. Lim, B. J. Yarbrough, B. K. P. M. Kankanamalage, G. R. Wilson, A. R. Hill, M. D. Smith, S. Garashchuk, A. B. Greytak, I. Aprahamian,* N. B. Shustova,* Confinement-Driven Photophysics in Hydrazone-Based Hierarchical Materials, Angew. Chem. Int. Ed. 2022, e202211776 Selected as VIP (Very Important Paper) |
75. Q. Qiu, S. Yang, M. A. Gerkman, H. Fu, I. Aprahamian,* G. G. D. Han,* Photon Energy Storage in Strained Cyclic Hydrazones: Emerging Molecular Solar Thermal Energy Storage Compounds, J. Am. Chem. Soc. 2022, 144, 12627–12631 |
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72. R. Liang, J. Samanta, B. Shao, M. Zhang, R. J. Staples, A. D. Chen, M. Tang, Y. Wu, I. Aprahamian,* C. Ke,* A Heteromeric Carboxylic-acid-based Single Crystalline Crosslinked Organic Framework, Angew. Chem. Int. Ed. 2021, 60, 23176-23181 Selected as VIP (Very Important Paper) |
71. S. Yang, D. Larsen, M. Pellegrini, S. Meier, D. F. Mierke,* S. R. Beeren,* I. Aprahamian,* Dynamic enzymatic synthesis of γ-cyclodextrin using a photoremovable hydrazone template, Chem 2021, 7, 2190-2200. Highlighted in C&EN, COSMOS, Dartmouth News,NRC and ChemistryWorld |
70. A. N. Bismillah,* I. Aprahamian,* Fundamental studies to emerging applications of pyrrole-BF2 (BOPHY) fluorophores, Chem. Soc. Rev. 2021, 50, 5631-5649 |
69. B. Shao, I. Aprahamian,* Hydrazones as New Molecular Tools, Chem 2020, 6, 2162-2173 |
68. I. Aprahamian,* The Future of Molecular Machines, ACS Cent. Sci. 2020, 6, 347-358 |
67. B. Shao, I. Aprahamian,* Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches, ChemistryOpen 2020, 9, 191-194 Contribution to a special issue dedicated to the 80th birthday of Jean-Marie Lehn |
66. X. Guo, B. Shao, S. Zhou, I. Aprahamian,* Z. Chen,* Visualizing intracellular particles and precise control of drug release using an emissive hydrazone photochrome, Chem. Sci. 2020, 11, 3016-3021 |
65. A. Iagatti, B. Shao, A. Credi, B. Ventura,* I. Aprahamian,* Di Donato, M., Ultrafast processes triggered by one- and two-photon excitation of a photochromic and luminescent hydrazone, Beilstein J. Org. Chem. 2019, 15, 2438–2446 |
64. L.-Q. Zheng, S. Yang, J. Lan, L. Gyr, G. Goubert, H. Qian, I. Aprahamian,* R. Zenobi,* Solution phase and surface photoisomerization of a hydrazone switch with long thermal half-life, J. Am. Chem. Soc. 2019, 141, 17637–17645 |
63. B. Shao, N. Stankewitz, J. A. Morris, M. D. Liptak, I. Aprahamian,* White-light emission from a structurally simple hydrazone, Chem. Commun. 2019, 5, 9551-9554 |
62. B. Shao, I. Aprahamian,* pH-Induced Fluorescence and Thermal Relaxation Rate Modulation in a Hydrazone Photoswitch, ChemPhotoChem 2019, 3, 361-364 Contribution to a special issue on Photoresponsive Molecular Switches and Machines |
61. B. Shao, H. Qian, Q. Li, I. Aprahamian,* Structure Property Analysis of the Solution and Solid-State Properties of Bistable Photochromic Hydrazones, J. Am. Chem. Soc. 2019, 141, 8364-8371 |
60. A. Ryabchun, Q. Li, F. Lancia, I. Aprahamian,* N. Katsonis,* Shape-Persistent Actuators from Hydrazone Photoswitches, J. Am. Chem. Soc. 2019, 141, 1196-1200 |
59. M. J. Moran, M. Magrini, D. M. Walba, I. Aprahamian,* Driving a Liquid Crystal Phase Transition Using a Photochromic Hydrazone, J. Am. Chem. Soc. 2018, 140, 13623-13627 |
58. B. Shao, M. Baroncini, H. Qian, L. Bussotti, M. Di Donato, A. Credi,* I. Aprahamian,* Solution and Solid-State Emission Toggling of a Photochromic Hydrazone, J. Am. Chem. Soc. 2018, 140, 12323-12327 Highlighted in C&EN |
57. Q. Li, H. Qian, B. Shao, Ru. P. Hughes, I. Aprahamian,* Building Strain with Large Macrocycles and Using It To Tune the Thermal Half-Lives of Hydrazone Photochromes, J. Am. Chem. Soc. 2018, 140, 11829-11835 Highlighted as spotlight |
56. J. D. Harris, M. J. Moran, I. Aprahamian,* New Molecular Switch Architectures, Proc. Natl. Acad. Sci. U.S.A. 2018, 115, 9414-9422 |
55. H. Qian, S. Pramanik, I. Aprahamian,* Photochromic Hydrazone Switches with Extremely Long Thermal Half-Lives, J. Am. Chem. Soc. 2017, 139, 9140-9143 |
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53. H. Qian, B. Shao, I. Aprahamian,* Visible-Light Fluorescence Photomodulation in Azo-BF2 Switches, Tetrahedron 2017, 73, 4901-4904 Invited contribution to the Tetrahedron Symposium-in-Print dedicated to Professor Ben Feringa |
52. V. Carboni, X. Su, H. Qian, I. Aprahamian,* A. Credi,* Blue-Light-Emitting Triazolopyridinium and Triazoloquinolinium Salts, ChemPhotoChem 2017, 1, 222-229 |
H. Qian, Y.-Y. Wang, D.-S. Guo, I. Aprahamian,* Controlling the Isomerization Rate of an Azo-BF2 Switch Using Aggregation , J. Am. Chem. Soc. 2017, 139, 1037-1040 |
50. H. Qian, E. M. Cousins, E. H. Horak, A. Wakefield, M. D. Liptak,* I. Aprahamian,* Suppression of Kasha's rule as a mechanism for fluorescent molecular rotors and aggregation-induced emission, Nature. Chem. 2017, 9, 83-87 This paper was highlighted in Science Daily, PhysOrg, and other news outlets. |
49. S. Pramanik, I. Aprahamian,* Hydrazone Switch-Based Negative Feedback Loop, J. Am. Chem. Soc. 2016, 138, 15142-15145 |
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47. H. Qian, I. Aprahamian,* An emissive and pH switchable hydrazone-based hydrogel, Chem. Commun. 2015, 51, 11158-11161 |
46. J. T. Foy, D. Ray, I. Aprahamian,* Regulating signal enhancement with coordination-coupled deprotonation of a hydrazone switch, Chem. Sci. 2015, 6, 209-213 |
45. L. Tatum, J. T. Foy, I. Aprahamian,* Waste management of chemically activated switches: using a photoacid to eliminate accumulation of side products, J. Am. Chem. Soc. 2014, 136, 17438-17441 This communication was highlighted in Science Daily, PhysOrg, and LaserFocusWorld. It was also featured in JACS Spotlights |
44. Y. Yang, R. P. Hughes, I. Aprahamian,* Near-Infrared Light Activated Azo BF2 Switches, J. Am. Chem. Soc. 2014, 136, 13190-13193. |
43. M.L. Croteau, X. Su, D. E. Wilcox, I. Aprahamian,* Metal Coordination and Isomerization of a Hydrazone Switch, ChemPlusChem 2014, 79, 1214-1224. Invited contribution to the Early Career Series |
42. L. Tatum, X. Su, I. Aprahamian,* Simple Hydrazone Building Blocks for Complicated Functional Materials, Acc. Chem. Res. 2014, 47, 2141-2149. Invited contribution to the special issue on Responsive Host Guest Systems. |
41. X. Su, I. Aprahamian,* Hydrazone-based switches, metallo-assemblies and sensors, Chem. Soc. Rev. 2014, 43, 1963-1981. Invited contribution to the special issue on Supramolecular and Dynamic Covalent Reactivity Check out the inside front cover. |
40. X. Su, I. Aprahamian,* Zinc(II)-Regulation of Hydrazone Switch Isomerization Kinetics, Org. Lett. 2013, 15, 5952-5955. |
39. X. Su, S. Voskian, R. P. Hughes, I. Aprahamian,* Manipulating Liquid-Crystal Properties Using a pH Activated Hydrazone Switch, Angew. Chem. Int. Ed. 2013, 52, 10734-10739. This communication was highlighted in C&EN , Medical News Today , Wiley-VCH Hot Topics , Chemistry Views, Liquid Crystals Today , and as a frontispiece. |
38. T. F. Robbins, H. Qian, X. Su, R. P. Hughes, I. Aprahamian,* Cyanide Detection Using a Triazolopyridinium Salt, Org. Lett. 2013, 15, 2386-2389. |
37. X. Su, M. Liptak, I. Aprahamian,* Water Soluble Triazolopyridinium Salts as Tunable Blue Light Emitters, Chem. Commun. 2013, 49, 4160-4162. Invited contribution to the 2013 Chem Commun Emerging Investigator Issue. |
36. Y. Yang, R. P. Hughes, I. Aprahamian,* Visible Light Switching of a BF2-Coordinated Azo Compound, J. Am. Chem. Soc. 2012, 134, 15221-15224. This communication was highlighted in C&EN. |
35. X. Su, M. Lokov, A. Kutt, I. Leito, I. Aprahamian,* Unusual para-Substituent Effects on the Intramolecular Hydrogen-Bond in Hydrazone-Based Switches, Chem. Commun. 2012, 48, 10490-10492. Invited contribution to the "Aromaticity" special issue. |
34. D. Ray, J. T. Foy, R. P. Hughes, I. Aprahamian,* A switching cascade of hydrazone-based rotary switches through coordination-coupled proton relays, Nature Chem. 2012, 4, 757-762. The paper was highlighted in the News and Views section of Nature Chemistry. |
33. X. Su, T. Lessing, I. Aprahamian,* The Importance of the Rotor in Hydrazone-Based Molecular Switches, Beilstein J. Org. Chem. 2012, 8, 872-876. Invited contribution to the "Molecular Switches and Cages" special issue. |
32. J. T. Foy, E. B. Wilkes, I. Aprahamian, Self-Assembly of Benzyl Cyclopentadienyl Lithium, CrystEngComm 2012, 14, 6126-6128. Invited contribution to the "New Talent Americas" special issue. |
31. Y. Yang, X. Su, C. Carroll, I. Aprahamian, Aggregation Induced Emission in BF2-Hydrazone (BODIHY) Complexes, Chem. Sci. 2012, 3, 610-613. This paper was one of the top 10 most accessed papers in November 2011. In addition, it was highlighted by ACS Noteworthy Chemistry. |
30. S. M. Landge, K. Tkatchouk, D. Benitez, D. A. Lanfranchi. M. Elhabiri, W. A. Goddard III, I. Aprahamian,* Isomerization Mechanism in Hydrazone-Based Rotary Switches: Lateral Shift, Rotation, or Tautomerization?, J. Am. Chem. Soc. 2011, 133, 9812-9823. |
29. X. Su, T. F. Robbins, I. Aprahamian,* Switching Through Coordination-Coupled Proton Transfer, Angew. Chem. Int. Ed. 2011, 50, 1841-1844. |
28. X. Su, I. Aprahamian,* Switching Around Two Axles: Controlling the Configuration and Conformation of a Hydrazone-Based Switch, Org. Lett. 2011, 31, 30-33. |
27. S. M. Landge, I. Aprahamian,* pH Activated Configurational Rotary Switch: Controlling the E/Z Isomerization in Hydrazones, J. Am. Chem. Soc. 2009, 131, 18269-18271. |
26. T. Yasuda, K. Tanabe, K. K. Coti, I. Aprahamian, J. F. Stoddart, T. Kato, A Redox-Switchable [2]Rotaxane in a Liquid-Crystalline State, Chem. Commun. 2010, 1224-1226.
This paper was selected as a Hot Paper and Highlighted in NPG Asia Materials.
25. A. Trabolsi, A. C. Fahrenbach, S. K. Dey, A. I. Share, D. C. Friedman, S. Basu, T. B. Gasa, N. M. Khashab, S. Saha, I. Aprahamian, H. A. Khatib, A. H. Flood, J. F. Stoddart, A Tristable [2]Pseudo[2]Rotaxane, Chem. Commun. 2010, 871-873.
24. Y.-L Zhao, W. R. Dichtel, A. H. Trabolsi, S. Saha, I. Aprahamian, J. F. Stoddart, A Redox-Switchable α-Cyclodextrin-Based [2]Rotaxane, J. Am. Chem. Soc. 2008, 130, 11294-11296.
23. W. R. Dichtel, O. Š. Miljanic, W. Zhang, J. M. Spruell, K. Patel, I. Aprahamian, J. R. Heath, J. F. Stoddart, Kinetic and Thermodynamic Approaches for the Efficient Formation of Mechanical Bonds, Acc. Chem. Res. 2008, 41, 1750-1761.
22. A. Coskun, S. Saha, I. Aprahamian, J. F. Stoddart, A Reverse Donor-Acceptor Bistable [2]Catenane, Org. Lett. 2008, 10, 3187-3190.
21. Y.-L. Zhao, I. Aprahamian, A. H. Trabolsi, N. Erina, J. F. Stoddart, Organogel Formation by a Cholesterol-Stoppered Bistable [2]Rotaxane and Its Dumbbell Precursor, J. Am. Chem. Soc. 2008, 130, 6348-6350.
20. I. Aprahamian, J.-C. Olsen, A. H. Trabolsi, J. F. Stoddart, Tetrathiafulvalene Radical Cation Dimerization in a Bistable Tripodal [4]Rotaxane, Chem. Eur. J. 2008, 14, 3889-3895.
19. O. Š. Miljanic, W. R. Dichtel, I. Aprahamian, R. D. Rohde, H. D. Agnew, J. R. Heath, J. F. Stoddart, Rotaxanes and Catenanes by Click Chemistry, QSAR Comb. Sci. 2007, 27, 1165-1174. (Invited Review)
18. I. Aprahamian, O. Š. Miljanic, W. R. Dichtel, K. Isoda, T. Yasuda, T. Kato, J. F. Stoddart, Clicked Interlocked Molecules, Bull. Chem. Soc. Jpn. 2007, 80, 1856-1869. (Invited Review - Back Cover)
17. S. Kang, I. Aprahamian, J. F. Stoddart, Pirouetting in Chiral [2]Catenanes, Israel J. Chem. 2007, 47, 253-262. (Equal contribution with S. K.)
16. I. Aprahamian, T. Yasuda, T. Ikeda, S. Saha, W. R. Dichtel, K. Isoda, T. Kato, J. F. Stoddart, A Liquid Crystalline Bistable [2]Rotaxane, Angew. Chem. Int. Ed. 2007, 46, 4675-4679.
15. T. Ikeda, I. Aprahamian, J. F. Stoddart, The Blue-Colored Donor-Acceptor [2]Rotaxane, Org. Lett. 2007, 9, 1481-1484.
14. I. Aprahamian, W. R. Dichtel, T. Ikeda, J. R. Heath, J. F. Stoddart, A Clicked Bistable [2]Rotaxane, Org. Lett. 2007, 9, 1287-1290.
13. T. Ikeda, S. Saha, I. Aprahamian, K. C.-F. Leung, A. Williams, W.-Q. Deng, A. H. Flood, W. A. Goddard III, J. F. Stoddart, Toward Electrochemically-Controllable Tristable Three-Station [2]Catenanes, Chem. Asian J. 2007, 2, 76-93.
12. S. Nygaard, K. C.-F. Leung, I. Aprahamian, T. Ikeda, S. Saha, B. W. Laursen, S.-Y. Kim, S. W. Hansen, P. C. Stein, A. H. Flood, J. F. Stoddart, J. O. Jeppesen, Functionally Rigid Bistable [2]Rotaxanes, J. Am. Chem. Soc. 2007, 129, 960-970.
11. R. J. Vermeil, D. O. Miller, L. N. Dawe, I. Aprahamian, T. Sheradsky, M. Rabinovitz, G. J. Bodwell, Mixed [2.2]Cyclophanes of Pyrene and Benzene, Aust. J. Chem. 2010, 63, 1703-1716.
10. I. Aprahamian, H. A. Wegner, T. Sternfeld, K. Rauch, A. de Meijere, T. Sheradsky, L. T. Scott, M. Rabinovitz, Anions and Polyanions of Oligoindenopyrenes: Modes of Electron Delocalization and Dimerization, Chem. Asian J. 2006, 1, 678-685.
9. A. de Meijere, B. Stulgies, K. Albrecht, K. Rauch, H. A. Wegner, H. Hopf, L. T. Scott, L. Eshdat, I. Aprahamian, M. Rabinovitz, New Interesting Molecular Topologies by Way of Modern Cross-Coupling Reactions, Pure Appl. Chem. 2006, 78, 813-830.
8. I. Aprahamian, D. V. Preda, M. Bancu, A. P. Belanger, T. Sheradsky, L. T. Scott, M. Rabinovitz, Reduction of Bowl-Shaped Hydrocarbons: Dianions and Tetraanions of Annelated Corannulenes, J. Org. Chem. 2006, 71, 290-298.
7. I. Aprahamian, D. Eisenberg, R. E. Hoffman, T. Sternfeld, Y. Matsuo, E. A. Jackson, E. Nakamura, L. T. Scott, T. Sheradsky, M. Rabinovitz, Ball-and-Socket Stacking of Supercharged Geodesic Polyarenes: Bonding by Interstitial Lithium Ions, J. Am. Chem. Soc. 2005, 127, 9581-9587.
6. I. Aprahamian, G. J. Bodwell, J. J. Fleming, G. P. Manning, M. R. Mannion, B. L. Merner, T. Sheradsky, R. J. Vermeij, M. Rabinovitz, Reduction of Strained Polycycles: How Much Strain Can a Pyrene Anion Take?, J. Am. Chem. Soc. 2004, 126, 6765-6775.
5. N. Treitel, R. Shenhar, I. Aprahamian, T. Sheradsky, M. Rabinovitz, Calculations of PAH anions: When Are Diffuse Functions Necessary?, Phys. Chem. Chem. Phys. 2004, 6, 1113-1121.
4. I. Aprahamian, G. J. Bodwell, J. J. Fleming, G. P. Manning, M. R. Mannion, T. Sheradsky, R. J. Vermeij, M. Rabinovitz, Reductive Dimerization of Tethered Pyrenes: Implications For the Reduction of Polycyclic Aromatic Hydrocarbons, Angew. Chem. Int. Ed. 2003, 42, 2547-2550.
This paper was designated a "VIP".
3. I. Aprahamian, G. J. Bodwell, J. J. Fleming, G. P. Manning, M. R. Mannion, T. Sheradsky, R. J. Vermeij, M. Rabinovitz, The Great Escape?from Antiaromaticity: Reduction of Strained Pyrenes, J. Am. Chem. Soc. 2003, 125, 1720-1721.
This paper was selected as an Editors' Choice by Science. See Science 2003, 299, 979-981.
2. I. Aprahamian, R. E. Hoffman, T. Sheradsky, D. V. Preda, M. Bancu, L. T. Scott, M. Rabinovitz, A Four-Step Alternating Reductive Dimerization/Bond-Cleavage of Indenocorannulene, Angew. Chem. Int. Ed. 2002, 41, 1712-1715.
1. T. Sternfeld, R. E. Hoffman, I. Aprahamian, M. Rabinovitz, Fullerene Anions: Unusual Charge Distribution in C₇₀⁶⁻, Angew. Chem. Int. Ed. 2001, 40, 455-457.
Book Chapter(s):
1. I. Aprahamian, M. Rabinovitz, "Polycyclic and Fullerene Lithium Carbanions" In The Chemistry of Organolithium Compounds (Vol II); Z. Rappoport, I. Marek, Eds; John Wiley & Sons Ltd.; Chichester (UK), 2006, 477-524.
2. B. Shao, I. Aprahamian, "Arylhydrazones" In Molecular Photoswitches; Z. L. Pianowski, Ed; Wiley, 2022, 113–129.
This paper was selected as a Hot Paper and Highlighted in NPG Asia Materials.
25. A. Trabolsi, A. C. Fahrenbach, S. K. Dey, A. I. Share, D. C. Friedman, S. Basu, T. B. Gasa, N. M. Khashab, S. Saha, I. Aprahamian, H. A. Khatib, A. H. Flood, J. F. Stoddart, A Tristable [2]Pseudo[2]Rotaxane, Chem. Commun. 2010, 871-873.
24. Y.-L Zhao, W. R. Dichtel, A. H. Trabolsi, S. Saha, I. Aprahamian, J. F. Stoddart, A Redox-Switchable α-Cyclodextrin-Based [2]Rotaxane, J. Am. Chem. Soc. 2008, 130, 11294-11296.
23. W. R. Dichtel, O. Š. Miljanic, W. Zhang, J. M. Spruell, K. Patel, I. Aprahamian, J. R. Heath, J. F. Stoddart, Kinetic and Thermodynamic Approaches for the Efficient Formation of Mechanical Bonds, Acc. Chem. Res. 2008, 41, 1750-1761.
22. A. Coskun, S. Saha, I. Aprahamian, J. F. Stoddart, A Reverse Donor-Acceptor Bistable [2]Catenane, Org. Lett. 2008, 10, 3187-3190.
21. Y.-L. Zhao, I. Aprahamian, A. H. Trabolsi, N. Erina, J. F. Stoddart, Organogel Formation by a Cholesterol-Stoppered Bistable [2]Rotaxane and Its Dumbbell Precursor, J. Am. Chem. Soc. 2008, 130, 6348-6350.
20. I. Aprahamian, J.-C. Olsen, A. H. Trabolsi, J. F. Stoddart, Tetrathiafulvalene Radical Cation Dimerization in a Bistable Tripodal [4]Rotaxane, Chem. Eur. J. 2008, 14, 3889-3895.
19. O. Š. Miljanic, W. R. Dichtel, I. Aprahamian, R. D. Rohde, H. D. Agnew, J. R. Heath, J. F. Stoddart, Rotaxanes and Catenanes by Click Chemistry, QSAR Comb. Sci. 2007, 27, 1165-1174. (Invited Review)
18. I. Aprahamian, O. Š. Miljanic, W. R. Dichtel, K. Isoda, T. Yasuda, T. Kato, J. F. Stoddart, Clicked Interlocked Molecules, Bull. Chem. Soc. Jpn. 2007, 80, 1856-1869. (Invited Review - Back Cover)
17. S. Kang, I. Aprahamian, J. F. Stoddart, Pirouetting in Chiral [2]Catenanes, Israel J. Chem. 2007, 47, 253-262. (Equal contribution with S. K.)
16. I. Aprahamian, T. Yasuda, T. Ikeda, S. Saha, W. R. Dichtel, K. Isoda, T. Kato, J. F. Stoddart, A Liquid Crystalline Bistable [2]Rotaxane, Angew. Chem. Int. Ed. 2007, 46, 4675-4679.
15. T. Ikeda, I. Aprahamian, J. F. Stoddart, The Blue-Colored Donor-Acceptor [2]Rotaxane, Org. Lett. 2007, 9, 1481-1484.
14. I. Aprahamian, W. R. Dichtel, T. Ikeda, J. R. Heath, J. F. Stoddart, A Clicked Bistable [2]Rotaxane, Org. Lett. 2007, 9, 1287-1290.
13. T. Ikeda, S. Saha, I. Aprahamian, K. C.-F. Leung, A. Williams, W.-Q. Deng, A. H. Flood, W. A. Goddard III, J. F. Stoddart, Toward Electrochemically-Controllable Tristable Three-Station [2]Catenanes, Chem. Asian J. 2007, 2, 76-93.
12. S. Nygaard, K. C.-F. Leung, I. Aprahamian, T. Ikeda, S. Saha, B. W. Laursen, S.-Y. Kim, S. W. Hansen, P. C. Stein, A. H. Flood, J. F. Stoddart, J. O. Jeppesen, Functionally Rigid Bistable [2]Rotaxanes, J. Am. Chem. Soc. 2007, 129, 960-970.
11. R. J. Vermeil, D. O. Miller, L. N. Dawe, I. Aprahamian, T. Sheradsky, M. Rabinovitz, G. J. Bodwell, Mixed [2.2]Cyclophanes of Pyrene and Benzene, Aust. J. Chem. 2010, 63, 1703-1716.
10. I. Aprahamian, H. A. Wegner, T. Sternfeld, K. Rauch, A. de Meijere, T. Sheradsky, L. T. Scott, M. Rabinovitz, Anions and Polyanions of Oligoindenopyrenes: Modes of Electron Delocalization and Dimerization, Chem. Asian J. 2006, 1, 678-685.
9. A. de Meijere, B. Stulgies, K. Albrecht, K. Rauch, H. A. Wegner, H. Hopf, L. T. Scott, L. Eshdat, I. Aprahamian, M. Rabinovitz, New Interesting Molecular Topologies by Way of Modern Cross-Coupling Reactions, Pure Appl. Chem. 2006, 78, 813-830.
8. I. Aprahamian, D. V. Preda, M. Bancu, A. P. Belanger, T. Sheradsky, L. T. Scott, M. Rabinovitz, Reduction of Bowl-Shaped Hydrocarbons: Dianions and Tetraanions of Annelated Corannulenes, J. Org. Chem. 2006, 71, 290-298.
7. I. Aprahamian, D. Eisenberg, R. E. Hoffman, T. Sternfeld, Y. Matsuo, E. A. Jackson, E. Nakamura, L. T. Scott, T. Sheradsky, M. Rabinovitz, Ball-and-Socket Stacking of Supercharged Geodesic Polyarenes: Bonding by Interstitial Lithium Ions, J. Am. Chem. Soc. 2005, 127, 9581-9587.
6. I. Aprahamian, G. J. Bodwell, J. J. Fleming, G. P. Manning, M. R. Mannion, B. L. Merner, T. Sheradsky, R. J. Vermeij, M. Rabinovitz, Reduction of Strained Polycycles: How Much Strain Can a Pyrene Anion Take?, J. Am. Chem. Soc. 2004, 126, 6765-6775.
5. N. Treitel, R. Shenhar, I. Aprahamian, T. Sheradsky, M. Rabinovitz, Calculations of PAH anions: When Are Diffuse Functions Necessary?, Phys. Chem. Chem. Phys. 2004, 6, 1113-1121.
4. I. Aprahamian, G. J. Bodwell, J. J. Fleming, G. P. Manning, M. R. Mannion, T. Sheradsky, R. J. Vermeij, M. Rabinovitz, Reductive Dimerization of Tethered Pyrenes: Implications For the Reduction of Polycyclic Aromatic Hydrocarbons, Angew. Chem. Int. Ed. 2003, 42, 2547-2550.
This paper was designated a "VIP".
3. I. Aprahamian, G. J. Bodwell, J. J. Fleming, G. P. Manning, M. R. Mannion, T. Sheradsky, R. J. Vermeij, M. Rabinovitz, The Great Escape?from Antiaromaticity: Reduction of Strained Pyrenes, J. Am. Chem. Soc. 2003, 125, 1720-1721.
This paper was selected as an Editors' Choice by Science. See Science 2003, 299, 979-981.
2. I. Aprahamian, R. E. Hoffman, T. Sheradsky, D. V. Preda, M. Bancu, L. T. Scott, M. Rabinovitz, A Four-Step Alternating Reductive Dimerization/Bond-Cleavage of Indenocorannulene, Angew. Chem. Int. Ed. 2002, 41, 1712-1715.
1. T. Sternfeld, R. E. Hoffman, I. Aprahamian, M. Rabinovitz, Fullerene Anions: Unusual Charge Distribution in C₇₀⁶⁻, Angew. Chem. Int. Ed. 2001, 40, 455-457.
Book Chapter(s):
1. I. Aprahamian, M. Rabinovitz, "Polycyclic and Fullerene Lithium Carbanions" In The Chemistry of Organolithium Compounds (Vol II); Z. Rappoport, I. Marek, Eds; John Wiley & Sons Ltd.; Chichester (UK), 2006, 477-524.
2. B. Shao, I. Aprahamian, "Arylhydrazones" In Molecular Photoswitches; Z. L. Pianowski, Ed; Wiley, 2022, 113–129.